孙湛, 刘岚铮, 郑敏, 张鑫, 张瑛, 崔亮亮, 王丽珩, 于志刚. 2021年济南市大气PM2.5中PAHs污染特征及其来源解析[J]. 环境卫生学杂志, 2024, 14(4): 343-349. DOI: 10.13421/j.cnki.hjwsxzz.2024.04.010
    引用本文: 孙湛, 刘岚铮, 郑敏, 张鑫, 张瑛, 崔亮亮, 王丽珩, 于志刚. 2021年济南市大气PM2.5中PAHs污染特征及其来源解析[J]. 环境卫生学杂志, 2024, 14(4): 343-349. DOI: 10.13421/j.cnki.hjwsxzz.2024.04.010
    SUN Zhan, LIU Lan-zheng, ZHENG Min, ZHANG Xin, ZHANG Ying, CUI Liang-liang, WANG Li-heng, YU Zhi-gang. Pollution characteristics and sources apportionment of PAHs in PM2.5 in Jinan, China, 2021[J]. Journal of Environmental Hygiene, 2024, 14(4): 343-349. DOI: 10.13421/j.cnki.hjwsxzz.2024.04.010
    Citation: SUN Zhan, LIU Lan-zheng, ZHENG Min, ZHANG Xin, ZHANG Ying, CUI Liang-liang, WANG Li-heng, YU Zhi-gang. Pollution characteristics and sources apportionment of PAHs in PM2.5 in Jinan, China, 2021[J]. Journal of Environmental Hygiene, 2024, 14(4): 343-349. DOI: 10.13421/j.cnki.hjwsxzz.2024.04.010

    2021年济南市大气PM2.5中PAHs污染特征及其来源解析

    Pollution characteristics and sources apportionment of PAHs in PM2.5 in Jinan, China, 2021

    • 摘要:
      目的 分析济南市2021年细颗粒物(fine particulate matter, PM2.5)中PAHs污染特征及来源分析, 为济南市大气环境综合治理提供相关数据支持。
      方法 根据济南市区域分布特点选取2个有代表性监测点, 每月的10—16日进行连续监测, 使用超高效液相色谱仪对16种PAHs进行检测, 分析济南市PM2.5中PAHs变化趋势及特征, 使用特征比值和PMF模型对PM2.5中PAHs进行源解析。
      结果 PAHs以4环和6环为主, 具有显著的季节性变化趋势, 即冬季>秋季>春季>夏季, 1月份污染情况尤为突出; 秋季和冬季中7种高致癌风险PAHs所占比例高于其他季节, 历城区各季节PAHs质量浓度均高于市中区; 结合特征比值和PMF对PAHs来源分析, 冬季主要污染源是工业和石油产品挥发源、交通源; 秋季主要为燃煤燃烧源、工业和石油产品挥发源和交通源。
      结论 济南市PM2.5中PAHs存在一定的污染, 需加大清洁能源的使用, 同时进一步加强秋、冬季, 尤其是采暖季燃煤燃烧、工业和石油产品挥发和交通等污染源的控制。

       

      Abstract:
      Objective To analyze the pollution characteristics and sources of polycyclic aromatic hydrocarbons (PAHs) in fine particulate matter (PM2.5) in Jinan, China, 2021, and to provide relevant data support for the comprehensive management of Jinan's atmospheric environment.
      Methods According to the regional distribution characteristics of Jinan city, two representative monitoring sites were selected for continuous monitoring from 10th to 16th of each month. The ultra-high performance liquid chromatograph was used to detect 16 PAHs species, analyze the change trend and characteristics of PAHs in PM2.5 in Jinan City, and use the feature ratio and PMF model to conduct source apportionment for PAHs in PM2.5.
      Results PAHs were mainly tetracyclic aromatic hydrocarbon and hexacyclic aromatic hydrocarbon, showed had a significant seasonal variation trend, that is, winter>autumn>spring>summer; with the pollution situation being particularly condition was especially prominent in January. In autumn and winter, the proportion of seven kinds of PAHs with high carcinogenic risk was higher than that in other seasons. The mass concentration of PAHs in all seasons in Licheng District was higher than that in the Shizhong District. According to the analysis of PAHs sources by characteristic ratio and PMF, the main pollution sources in winter are volatile sources of industrial and petroleum products and traffic sources. Autumn is mainly for coal combustion sources, industrial and petroleum products volatile sources and transportation sources.
      Conclusion There is certain pollution of PAHs in PM2.5 in Jinan, so it is necessary to increase the use of clean energy. At the same time, further strengthen the control of coal combustion, industrial and petroleum products volatilization and traffic pollution sources in autumn and winter, especially in heating season.

       

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