许珉. 离子色谱法同时测定生活饮用水中五种常见消毒副产物和草甘膦[J]. 环境卫生学杂志, 2022, 12(4): 298-303. DOI: 10.13421/j.cnki.hjwsxzz.2022.04.009
    引用本文: 许珉. 离子色谱法同时测定生活饮用水中五种常见消毒副产物和草甘膦[J]. 环境卫生学杂志, 2022, 12(4): 298-303. DOI: 10.13421/j.cnki.hjwsxzz.2022.04.009
    XU Min. Simultaneous determination five common disinfection by-products and glyphosate in drinking water using ion chromatography[J]. Journal of Environmental Hygiene, 2022, 12(4): 298-303. DOI: 10.13421/j.cnki.hjwsxzz.2022.04.009
    Citation: XU Min. Simultaneous determination five common disinfection by-products and glyphosate in drinking water using ion chromatography[J]. Journal of Environmental Hygiene, 2022, 12(4): 298-303. DOI: 10.13421/j.cnki.hjwsxzz.2022.04.009

    离子色谱法同时测定生活饮用水中五种常见消毒副产物和草甘膦

    Simultaneous determination five common disinfection by-products and glyphosate in drinking water using ion chromatography

    • 摘要:
      目的 建立离子色谱法同时测定生活饮用水中亚氯酸盐、氯酸盐、溴酸盐、二氯乙酸和三氯乙酸5种常见消毒副产物和草甘膦含量的方法。
      方法 水样依次经OnGuard Ag/Ba/H柱和0.22 μm滤膜后上机,利用淋洗液在线发生装置实现梯度洗脱,在IonPac AS19柱上得到有效分离,经抑制器降低背景值后用电导检测器检测。
      结果 亚氯酸盐、氯酸盐、二氯乙酸、三氯乙酸和草甘膦在(5~200)μg/L, 溴酸盐在(1~40)μg/L范围内线性良好,r≥0.999 5,检出限均低于现行国标要求,加标回收率为95.3%~108.5%,相对标准偏差均小于5%,能满足实际样品检测需求。
      结论 该方法操作简单、分离效果好、灵敏度高,适用于生活饮用水日常监测任务。

       

      Abstract:
      Objective To establish an ion chromatography (1C) method for simultaneous determination of the content of five common disinfection by-products and glyphosate in drinking water.
      Methods The water samples were determined after going through the OnGuard Ag/Ba/H column and 0.22 μm filter membrane; Gradient elution was achieved using an online eluent generator; The result ants were effectively separated on the IonPac AS19 column and then tested by a conductivity detector after reduction of the background value by a suppressor.
      Results A Good linearity was observed for chlorite, chlorate, dichloroacetic acid, trichloroacetic acid, and glyphosate within the range of 5-200 μg/L, and for bromates within the range of 1-40 μg/L, with r ≥0.999 5; All the detection limits of the method were lower than the requirements of the current national standard in China; and the spike recovery rates were 95.3%-109%, with all the relative standard deviations less than 5%. The method could meet thus meeting the requirements for practical sample testing.
      Conclusion The method is suitable for daily surveillance of drinking water due to its simple operation, good separation, and high sensitivity.

       

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